Draw the best Lewis structure for CH2F2. Which of the following is/are true? Select all that apply.
CHF2 is nonpolar
There are dispersion forces between two CH2F2 molecules
There are dipole-dipole forces between two CH2F2 molecules
There is hydrogen bonding between two CH2F2 molecules
The strongest intermolecular force between two CH2F2 molecules is ion-dipole forces
CHF2 should have a lower boiling point than CH4
The molecular geometry for CH2F2 is tetrahedral
The correct answer and explanation is :
To analyze CH₂F₂ (difluoromethane), let’s first draw its Lewis structure and evaluate its properties.
Lewis Structure of CH₂F₂:
Carbon (C) is the central atom:
- Carbon forms 4 single bonds: 2 with H atoms, and 2 with F atoms.
- Each H has 1 bond (full shell).
- Each F has 3 lone pairs (6 electrons) and 1 bond to C.
So, the structure looks like:
H
|
F - C - F
|
H
Molecular Geometry:
Using VSEPR theory, CH₂F₂ has 4 bonding regions and no lone pairs on carbon, resulting in a tetrahedral geometry.
Polarity:
- Fluorine is much more electronegative than hydrogen, so the C–F bonds are strongly polar.
- The molecule is not symmetrical because the F atoms are not evenly distributed around the carbon.
- Dipoles do not cancel out, so CH₂F₂ is polar.
Intermolecular Forces:
- Dispersion forces: Always present in all molecules.
- Dipole-dipole forces: Present due to polarity.
- Hydrogen bonding: Requires H bonded to N, O, or F within the same molecule, which CH₂F₂ lacks. So, no hydrogen bonding between molecules.
- Ion-dipole forces: Occur between ions and polar molecules—not applicable here since CH₂F₂ is neutral.
Boiling Point Comparison (CH₂F₂ vs CH₄):
- CH₄ (methane) is nonpolar, has only dispersion forces, and a very low boiling point (−161°C).
- CH₂F₂ is polar with dipole-dipole interactions → higher boiling point than CH₄.
✅ Correct Statements:
- ✅ There are dispersion forces between two CH₂F₂ molecules.
- ✅ There are dipole-dipole forces between two CH₂F₂ molecules.
- ✅ The molecular geometry for CH₂F₂ is tetrahedral.
❌ Incorrect Statements:
- ❌ CHF₂ is nonpolar → CH₂F₂ is polar.
- ❌ There is hydrogen bonding → No H bonded to O/N/F in this context.
- ❌ Strongest force is ion-dipole → No ions present.
- ❌ CHF₂ has lower boiling point than CH₄ → CH₂F₂ has a higher boiling point.